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請使用永久網址來引用或連結此文件:
http://ir.cmu.edu.tw/ir/handle/310903500/30630
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| 題名: | Efficacy of pelvic floor rehabilitation for treatment of genuine stress incontinence |
| 作者: | Chen, HY;Chang, WC;Lin, WC;Yeh, LS;Hsu, TY;Tsai, HD;Yang, KY |
| 貢獻者: | 醫學院醫學系寄生蟲學科;China Med Coll Hosp, Dept Obstet & Gynecol, Taichung, Taiwan;China Med Coll Hosp, Urodynam Unit, Taichung, Taiwan |
| 日期: | 1999 |
| 上傳時間: | 2010-09-24 14:58:57 (UTC+8) |
| 出版者: | EXCERPTA MEDICA ASIA LTD |
| 摘要: | Under mild conditions, reactions of (CO)(5)M=C[N(R)CH2](2) [M = W, Mo, Cr; R = Et, allyl, benzyl, 4-pentenyl] with (PhCN)(2)PdCl2, (PhCN)(2)PtCl2, [(CO)(2)RhCl](2), (Me2S)AuCl, [(CH3CN)(4)Cu]BF4, and AgBF4 provide the corresponding diaminocarbene complexes via carbene ligand transfer. The resulting Pd(II), Pt(II), Rh(I), and Au(I) carbene complexes are stable and were isolated. The Cu(I) and Ag(I) complexes readily undergo acid-induced M=C cleavage to yield the imidazolidin-2-ylidinium salts. The carbene-transfer reactions were studied for two phosphine donors: (CO)(m)(L)W=C[N(R)CH2](2) CR = Et, benzyl; L = PPh3, m = 4; L = dppe, m = 3). The X-ray crystal structures of (CO)(5)W=C[N(CH2C6H5)CH2](2) (1c), cis-(CO)(4)(PPh3)W=C[N(CH2C6H5)CH2](2) (5b), fac-(CO)(3)(dppe)W=C[N(CH2C6H5)CH2](2) (6b), Cl-2(CO)Pt=C[N(CH2C6H5)CH2](2) (9c), and cis-Cl2Pt{=C[N(CH2C6H5)CH2](2)}(2) (11b) are reported. |
| 關聯: | JOURNAL OF THE FORMOSAN MEDICAL ASSOCIATION 98(4):271-276 |
| 顯示於類別: | [醫學系] 期刊論文
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