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    CMUR > College of Medicine > School of Medicine > Journal articles >  Item 310903500/30630
    Please use this identifier to cite or link to this item: http://ir.cmu.edu.tw/ir/handle/310903500/30630


    Title: Efficacy of pelvic floor rehabilitation for treatment of genuine stress incontinence
    Authors: Chen, HY;Chang, WC;Lin, WC;Yeh, LS;Hsu, TY;Tsai, HD;Yang, KY
    Contributors: 醫學院醫學系寄生蟲學科;China Med Coll Hosp, Dept Obstet & Gynecol, Taichung, Taiwan;China Med Coll Hosp, Urodynam Unit, Taichung, Taiwan
    Date: 1999
    Issue Date: 2010-09-24 14:58:57 (UTC+8)
    Publisher: EXCERPTA MEDICA ASIA LTD
    Abstract: Under mild conditions, reactions of (CO)(5)M=C[N(R)CH2](2) [M = W, Mo, Cr; R = Et, allyl, benzyl, 4-pentenyl] with (PhCN)(2)PdCl2, (PhCN)(2)PtCl2, [(CO)(2)RhCl](2), (Me2S)AuCl, [(CH3CN)(4)Cu]BF4, and AgBF4 provide the corresponding diaminocarbene complexes via carbene ligand transfer. The resulting Pd(II), Pt(II), Rh(I), and Au(I) carbene complexes are stable and were isolated. The Cu(I) and Ag(I) complexes readily undergo acid-induced M=C cleavage to yield the imidazolidin-2-ylidinium salts. The carbene-transfer reactions were studied for two phosphine donors: (CO)(m)(L)W=C[N(R)CH2](2) CR = Et, benzyl; L = PPh3, m = 4; L = dppe, m = 3). The X-ray crystal structures of (CO)(5)W=C[N(CH2C6H5)CH2](2) (1c), cis-(CO)(4)(PPh3)W=C[N(CH2C6H5)CH2](2) (5b), fac-(CO)(3)(dppe)W=C[N(CH2C6H5)CH2](2) (6b), Cl-2(CO)Pt=C[N(CH2C6H5)CH2](2) (9c), and cis-Cl2Pt{=C[N(CH2C6H5)CH2](2)}(2) (11b) are reported.
    Relation: JOURNAL OF THE FORMOSAN MEDICAL ASSOCIATION 98(4):271-276
    Appears in Collections:[School of Medicine] Journal articles

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