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    題名: 中部都市垃圾焚化爐周界空氣中之垂直重金屬濃度分布及污染來源探討
    作者: 劉心縵;Shin-Man Liu
    貢獻者: 中國醫藥大學:環境醫學研究所碩士班
    關鍵詞: 都市垃圾焚化爐;繫留氣球;垂直採樣;微粒;因素分析;Municipal solid waste incinerator;tethered balloon;vertical sampling;aerosol;factor analysis
    日期: 2006-06-20
    上傳時間: 2009-08-11 16:56:22 (UTC+8)
    摘要: 本研究為了建立焚化爐週邊垂直剖面重金屬濃度之數據,並瞭解都會垃圾焚化爐周界空氣中重金屬之濃度及其污染特性分布,分別於2005年3月及7月距離該焚化爐西南方下風處約800公尺之處,利用繫留氣球進行二次垂直採樣,氣球釋放至高度150公尺,每50公尺設一採樣點,收集不同粒徑大小之粉塵並分析微粒中十六種重金屬之濃度。結果顯示,濃度較高之金屬元素為鎂,而對健康危害較大之重金屬,鉛、錳、鉻、砷、鎘皆<0.1 μg/m3 ,比較二次之濃度差異性時,於細粒徑(PM2 )中之重金屬濃度達統計上顯著差異(p-value<0.05),其次依序為PM2-10 、PM10。於粒徑成分上,第一次採樣中PM2 成分約佔40-60%、PM2-10 約佔20-40%、PM10則為10-20%;較特別的是第二次採樣,Pb在0、50、100米高度細粒徑部分超過80%以上,經分析數據發現晨間所收集到之濃度最高;在高度分析上Al、Fe、Zn在100m高度之濃度為最高,50公尺高度為最低,另Pb、Mn、Ba、Ni、Cd粒徑在2μm時卻發現皆為地面之濃度較高。
    在因素分析上,依其因素解釋力依序歸納為:粒徑<2μm主要為街塵/營建、工業及交通之影響為大:而粒徑2-10μm為街塵/營建、工業之影響較大;而粒徑>10μm則主要受到土壤揚塵及交通之影響。整體而言,採樣地區周圍可能污染源有土壤揚塵/營建工程、交通移動源、工業等影響此次採樣結果。
    因此推論當時除了當地之污染源外,可能也有交通及其他工業之排放以及其他污染源經由中、長程傳輸影響此次採樣結果。

    In order to understand the ambient air concentration of heavy metals in the vicinity of a solid waste incinerator in central Taiwan, a monitoring program was implemented. Samples were taken in March and July, 2005. The sampling site is located at southwest of incinerator and is 800 m from incinerator. The sampler was carried by a tethered balloon up to 150 meters height to take aerosol sample. Sampling was conducted by installing a personal cascade impactor at each 50 meter to take aerosol sample at that level . Then,the analysis of concentrations of 16 metal elements was performed. The results showed that Mg has the highest concentration than other elements. For the elements with toxic effect on human, such as Pb, Mn, Cr, As, and Cd, their concentrations were all below 0.1 μg/m3.
    Characteristic size distributions allowed identification of three main behavioral type: 1.metal composition in fine particles constitute the major part of total particles. 2.at second sampling found Pb in 0、50、100 meters level height over 80%,respectively.3.in 100 meters element Al、Fe、Zn were higher than others.But element Pb、Mn、Ba、Ni、Cd in the 2μm aerodynamic size were found high concentrations in the ground.
    The study makes use of factor analysis to qualitatively categorize potential pollution sources of ambient particulate matter.The PM2 might be influenced by the soil dust ,industry , and vehicular emissions;PM2-10 were connected to soil dust and industry emissions,PM10 to be related to soil dust,vehicular emissions.
    Combining the results from characteristic size distributions and factor analysis, it suggests that results might be due to the different sources,such as soil dust,traffic and industy to influence the sampling area.
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