A new alkaloid of hydro-oxadiazine with a four-ring fused structure has been isolated from Fissistigma oldhamii (Memsl.) Merr. (Annonaceae) and named fissoldhimine (1), the structure of which was solved by X-ray analysis. NMR spectra were assigned based on the established structure, and its possible biogenesis is also discussed.
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CHEMICAL & PHARMACEUTICAL BULLETIN 42(10):2202-2204